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Solution reactivity studies of group 15 Zintl ions

Abstract:

The reactivity of group 15 Zintl ions, E73– (E = P, As), towards a number of transition and post-transition metal reagents has been studied. The synthesis and characterisation of the resulting novel cluster anions are described herein.

The reactions of E73– with [Cu5(mes)5], MPh2 (M = Zn, Cd) and InPh3 yielded the Cu–Cu bridged species [Cu2(E7)2]4– (E =...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Corpus Christi College
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
Subjects:
UUID:
uuid:0196fc28-2915-45f4-878d-12a6a1f01129
Local pid:
ora:7665
Deposit date:
2013-12-11

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