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Thesis

Asymmetric rhodium catalysed arylation: from ligand design to application

Abstract:

This thesis focuses on the development of highly enantioselective rhodium catalysed arylation reactions on small, unsaturated carbocycles and on work towards the development of novel scaffolds for diene ligands applicable in asymmetric rhodium catalysis.

The synthesis and evaluation of a new type of diene ligand, which is based on a structure obtained as the product of a rhodium catalysed allylic arylation of racemic halides, is reported. Two different prototype ligands were desig...

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Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author

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Role:
Supervisor
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Programme:
Fully funded studentship from the Department of Chemistry and Covid-19 extension funding from the MPLS
Funding agency for:
Hell, AML
Grant:
n/a
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
Subjects:
Deposit date:
2021-07-01

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