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Reactivity of a dititanium bis(pentalene) complex toward heteroallenes and main-group element–element bonds

Abstract:

The reactivity of the Ti=Ti double bond in (μ,η 5 :η 5 -Pn † ) 2 Ti 2 (1; Pn † = 1,4-{Si i Pr 3 } 2 C 8 H 4 ) toward isocyanide and heteroallene substrates, and molecules featuring homonuclear bonds between main-group elements (E-E) has bee n explored. Reaction of 1 with methyl isocyanide or 1,3-N,N′-di-p-tolylcarbodiimide resulted in the formation of the 1:1 adducts (μ,η 5 :η 5 -Pn † ) 2 Ti 2 (μ,η 2 -CNMe) (2) and (μ,η 5 :η 5 -Pn † ) 2 Ti 2 (μ-C{N(4-C 6 H 4 CH 3 )} 2 ) (3), respectively, w...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.organomet.6b00791

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Hugh's College
Role:
Author
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Role:
Author
ORCID:
0000-0001-7822-6593
University of Sussex More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
36
Issue:
2
Pages:
352-362
Publication date:
2016-12-20
Acceptance date:
2016-12-20
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Source identifiers:
694063
Keywords:
Pubs id:
pubs:694063
UUID:
uuid:131346af-40e3-4c42-9fbf-259f8f5054e1
Local pid:
pubs:694063
Deposit date:
2017-12-01

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