Journal article icon

Journal article

Synchrotron-Based Infrared Microanalysis of Biological Redox Processes under Electrochemical Control.

Abstract:

We describe a method for addressing redox enzymes adsorbed on a carbon electrode using synchrotron infrared microspectroscopy combined with protein film electrochemistry. Redox enzymes have high turnover frequencies, typically 10-1000 s(-1), and therefore, fast experimental triggers are needed in order to study subturnover kinetics and identify the involvement of transient species important to their catalytic mechanism. In an electrochemical experiment, this equates to the use of microelectro...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1021/acs.analchem.6b00898

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Expand authors...
More from this funder
Grant:
EnergyBioCatalysis-ERC-2010-StG-258600
More from this funder
Grant:
EP/K031503/1; INSPIRE award EP/J015202/1; EP/J500495/1; EP/L505031/1
European Molecular Biology Organization More from this funder
Expand funders...
Publisher:
American Chemical Society Publisher's website
Journal:
Analytical Chemistry Journal website
Volume:
88
Issue:
13
Pages:
6666-6671
Publication date:
2016-06-07
Acceptance date:
2016-06-07
DOI:
EISSN:
1520-6882
ISSN:
0003-2700
Pmid:
27269716
Source identifiers:
626337
Language:
English
Keywords:
Pubs id:
pubs:626337
UUID:
uuid:1fd9b9ec-4f42-478e-b8f7-e763b9725c06
Local pid:
pubs:626337
Deposit date:
2017-02-02

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP