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Amidinato- and guanidinato-cobalt(I) complexes: characterization of exceptionally short Co-Co interactions.

Abstract:
CoCo loco! Ligand-bridged dimers (see picture) with the shortest known Co-Co interactions are the first amidinato and guanidinato cobalt(I) complexes. The nature of the interactions has been probed by magnetic and theoretical investigations, and has been shown to be multiconfigurational. Preliminary reactivity studies of the complexes have also been carried out. © 2009 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200900780

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
48
Issue:
40
Pages:
7406-7410
Publication date:
2009-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
41403
Language:
English
Keywords:
Pubs id:
pubs:41403
UUID:
uuid:3029db53-0080-4249-88ab-5ec2ba024f70
Local pid:
pubs:41403
Deposit date:
2012-12-19

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