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Mapping and tuning the fluorescence of perfluorinated polyanilines synthesized through liquid-liquid interfaces

Abstract:

A series of light-emitting perfluorinated polyanilines were synthesized by the oxidative polymerization of 3-perfluorooctyl aniline through a variety of aqueous/organic interfaces. According to the interfacial tension between the two solvents (the organic being chloroform, dichloromethane, perfluorinated ethers, toluene or o-dichlorobenzene, we obtain distinctive classes of materials based on the crystal packing, protonation and oxidation state of the polymeric chains. We distinguish between ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.jpcb.6b00739

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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
Publisher:
ACS Publications Publisher's website
Journal:
Journal of Physical Chemistry B Journal website
Volume:
120
Issue:
13
Pages:
3441-3454
Publication date:
2016-03-10
Acceptance date:
2016-03-04
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Source identifiers:
611757
Language:
English
Pubs id:
pubs:611757
UUID:
uuid:30888000-18cc-4ad3-a717-0809aa46573b
Local pid:
pubs:611757
Deposit date:
2016-04-04

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