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Structural complexity in Prussian blue analogues

Abstract:

We survey the most important kinds of structural complexity in Prussian blue analogues, their implications for materials function, and how they might be controlled through judicious choice of composition. We focus on six particular aspects: octahedral tilts, A-site 'slides', Jahn–Teller distortions, A-site species and occupancy, hexacyanometallate vacancies, and framework hydration. The promising K-ion cathode material KxMn[Fe(CN)6]y serves as a recurrent example that illustrates many of thes...

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Publication status:
In press
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/d1mh01124c

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
St Anne's College
Role:
Author
ORCID:
0000-0001-9231-3749
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Materials Horizons Journal website
Publication date:
2021-10-22
Acceptance date:
2021-10-21
DOI:
EISSN:
2051-6355
ISSN:
2051-6347
Language:
English
Keywords:
Pubs id:
1205784
Local pid:
pubs:1205784
Deposit date:
2021-10-25

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