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New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands

Abstract:

Several new P or As compounds containing the 2,4,6-(CF3)3C6H2 (Ar), 2,6-(CF3)2C6H3 (Ar′) and/or 2,4-(CF3)2C6H3 (Ar″) ligands have been synthesised, and characterised by multinuclear NMR spectroscopy and (for all isolated compounds) elemental analysis. The crystal and molecular structures of ArPBr2 1, Ar2PCl 2, Ar″2PCl 3, Ar″2PBr 4, Ar′ Ar″ AsCl 5, Ar′ Ar″ AsBr 6 and Ar′ Ar″ AsH 7 have been determined by single-crystal X-ray diffraction. A particularly interesting feature of these structures i...

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Publication status:
Published

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Publisher copy:
10.1039/b207327g

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
24
Pages:
4622-4628
Publication date:
2002-01-01
DOI:
EISSN:
1364-5447
ISSN:
1472-7773
Source identifiers:
117228
Language:
English
Pubs id:
pubs:117228
UUID:
uuid:3800e9c5-1525-49ec-84df-1ae53d71f490
Local pid:
pubs:117228
Deposit date:
2012-12-19

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