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Unscrambling illusory inhibition and catalysis in nanoparticle electrochemistry: experiment and theory

Abstract:

Recent theoretical work (Applied Materials Today 15 (2019), pp. 139-144) has demonstrated that the cyclic voltammetry of particle-modified electrodes bears a significant level of complexity: Altered mass transport inside the porous layer gives rise to effects that may falsely suggest positive or negative catalysis. This communication reports experimental work that validates this theory. Using the well-studied oxidation of ferrocenemethanol at glassy carbon, we describe experiments in the pres...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.apmt.2019.05.002

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Oxford college:
St John's College
Role:
Author
Publisher:
Elsevier Publisher's website
Journal:
Applied Materials Today Journal website
Volume:
16
Pages:
141-145
Publication date:
2019-05-22
Acceptance date:
2019-05-02
DOI:
ISSN:
2352-9407
Source identifiers:
1003342
Language:
English
Keywords:
Pubs id:
pubs:1003342
UUID:
uuid:38147e6c-03e6-4592-b473-f5cd612995f9
Local pid:
pubs:1003342
Deposit date:
2019-05-30

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