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Structural and photophysical properties of coordination networks combining [Ru(bipy)(CN)4]2- anions and lanthanide(III) cations: rates of photoinduced Ru-to-lanthanide energy transfer and sensitized near-infrared luminescence.

Abstract:

Co-crystallization of K2[Ru(bipy)(CN)4] with lanthanide(III) salts (Ln = Pr, Nd, Gd, Er, Yb) from aqueous solution affords coordination oligomers and networks in which the [Ru(bipy)(CN)4]2- unit is connected to the lanthanide cation via Ru-CN-Ln bridges. The complexes fall into two structural types: [{Ru(bipy)(CN)4}2{Ln(H2O)m}{K(H2O)n}] x xH2O (Ln = Pr, Er, Yb; m = 7, 6, 6, respectively), in which two [Ru(bipy)(CN)4]2- units are connected to a single lanthanide ion by single cyanide bridges t...

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Publication status:
Published

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Publisher copy:
10.1021/ic050512k

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
44
Issue:
13
Pages:
4656-4665
Publication date:
2005-06-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
39559
Language:
English
Pubs id:
pubs:39559
UUID:
uuid:389f8cc7-d39f-41e8-b9d6-039838064e61
Local pid:
pubs:39559
Deposit date:
2012-12-19

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