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Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

Abstract:
The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K () and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J'/J| = 3.3 × 10-3, demonstrating a high degree of isolation for the Cu chains.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c8cp07160h

Authors


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Role:
Author
ORCID:
0000-0001-8584-105X
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Role:
Author
ORCID:
0000-0002-6714-4215
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
ORCID:
0000-0002-0666-5236
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Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Physical Chemistry Chemical Physics Journal website
Volume:
21
Pages:
1014-1018
Publication date:
2018-12-14
Acceptance date:
2018-12-14
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Pmid:
30574636
Source identifiers:
954927
Language:
English
Pubs id:
pubs:954927
UUID:
uuid:39621b20-3ac5-4d33-9d37-43d1ebae5df0
Local pid:
pubs:954927
Deposit date:
2019-01-23

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