Journal article
Microdisk electrode voltammetry: Theoretical characterization and experimental verification of a novel electrocatalytic mechanism
- Abstract:
-
A numerical method is used to characterize the steady-state voltammetry at microdisk electrodes of a new electrocatalytic reaction. This reaction, which occurs for the oxidation of MW-dimethylphenylenediamine (DMPD, A) in the presence of H2S (X) is believed to proceed via the following route: A -2e- B, B + X → B-X (k2), B-X -2e- [B-X]2+. Due to the presence of a reagent restricted homogeneous kinetic step, the reaction is labeled EC2xE. The numerical method for simulating this reaction scheme...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/jp002772n
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Authors
Bibliographic Details
- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY B
- Volume:
- 104
- Issue:
- 47
- Pages:
- 11258-11267
- Publication date:
- 2000-11-30
- DOI:
- EISSN:
-
1520-5207
- ISSN:
-
1089-5647
- Source identifiers:
-
37675
Item Description
- Language:
- English
- UUID:
-
uuid:399f5f8d-bb47-4d9c-80e8-b3f80c2f9039
- Local pid:
- pubs:37675
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2000
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