Journal article icon

Journal article

Microdisk electrode voltammetry: Theoretical characterization and experimental verification of a novel electrocatalytic mechanism

Abstract:

A numerical method is used to characterize the steady-state voltammetry at microdisk electrodes of a new electrocatalytic reaction. This reaction, which occurs for the oxidation of MW-dimethylphenylenediamine (DMPD, A) in the presence of H2S (X) is believed to proceed via the following route: A -2e- B, B + X → B-X (k2), B-X -2e- [B-X]2+. Due to the presence of a reagent restricted homogeneous kinetic step, the reaction is labeled EC2xE. The numerical method for simulating this reaction scheme...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/jp002772n

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY B
Volume:
104
Issue:
47
Pages:
11258-11267
Publication date:
2000-11-30
DOI:
EISSN:
1520-5207
ISSN:
1089-5647
Source identifiers:
37675
Language:
English
UUID:
uuid:399f5f8d-bb47-4d9c-80e8-b3f80c2f9039
Local pid:
pubs:37675
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP