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Nitric oxide decomposition on small rhodium clusters, Rh(n)+/-

Abstract:

The decomposition of nitric oxide on small charged rhodium clusters Rh(n)(+/-) (6 < n < 30) has been investigated by Fourier transform ion cyclotron resonance mass spectrometry. For both cationic and anionic naked clusters, the rates of reaction with NO increase smoothly with cluster size in the range studied without the dramatic size-dependent fluctuations often associated with the reactions of transition-metal clusters. The cationic clusters react significantly faster than the anions ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/jp062178z

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Publisher:
American Chemical Society Publisher's website
Journal:
Journal of Physical Chemistry A Journal website
Volume:
110
Issue:
38
Pages:
10992-11000
Publication date:
2006-09-07
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
Pmid:
16986831
Source identifiers:
58986
Language:
English
Keywords:
Pubs id:
pubs:58986
UUID:
uuid:3f2e3a40-e4b5-4bdd-b737-5b92b2333d49
Local pid:
pubs:58986
Deposit date:
2017-02-17

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