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Iron-mediated cleavage of C-C bonds in vicinal tricarbonyl compounds in water.

Abstract:
Three of a kind: Vicinal tricarbonyl compounds undergo C-C cleavage mediated by ferric ions (see scheme). The observed cleavage of ninhydrin and dehydroascorbic acid has relevance for amino acid detection and the metabolism of vitamin C.
Publication status:
Published

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Publisher copy:
10.1002/anie.200806296

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
48
Issue:
15
Pages:
2796-2800
Publication date:
2009-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
34642
Language:
English
Keywords:
Pubs id:
pubs:34642
UUID:
uuid:3f54a355-da7d-4cbc-a355-6df28499d7d9
Local pid:
pubs:34642
Deposit date:
2012-12-19

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