Investigating the chemistry of cationic rhodium bisphosphine complexes: comparing reactivity in the solid state with solution
This thesis describes the synthesis and characterisation of a series of cationic rhodium bis-phosphine complexes. The reactivity of these new complexes in the solid-state and in solution is reported.
In Chapter 2 the synthesis of a series of rhodium bis-phosphine diene complexes is presented and the reactions of these complexes with hydrogen in the solid-state are investigated. Several examples of zwitterionic complexes coordinating the [BArF4]─...Expand abstract
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- Oxford University, UK
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- Sebastian D. Pike
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