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High energy X-rays for following metal-organic framework formation: identifying intermediates in interpenetrated MOF-5 crystallisation

Abstract:

We report a study of the solvothermal formation of the interpenetrated form of the zinc 1,4-benzene dicarboxylate (BDC) metal organic framework MOF-5 using high-energy in situ X-ray diffraction (λ = 0.2333 Å, 53.14 keV). This method allows penetration of a Teflon-lined stainless steel reaction vessel to measure high-resolution powder patterns at 60 s intervals from which temporal evolution of lattice parameters and Bragg peak area can be refined. Crystallisation in N,N-dimethylformamide (DMF)...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.micromeso.2017.04.043

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Institution:
University of Oxford
Oxford college:
Balliol College
Role:
Author
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Grant:
FP7-NMP4-LA-2012-280983
Publisher:
Elsevier Publisher's website
Journal:
Microporous and Mesoporous Materials Journal website
Volume:
254
Pages:
178-183
Publication date:
2017-04-22
Acceptance date:
2017-04-19
DOI:
ISSN:
1387-1811
Source identifiers:
696609
Keywords:
Pubs id:
pubs:696609
UUID:
uuid:42328647-21ed-47f6-a921-4f1a99f9643b
Local pid:
pubs:696609
Deposit date:
2017-08-16

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