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Thesis

The synthesis and characterisation of metal complexes containing chemically reduced bipyridyl ligand systems

Abstract:

This thesis describes the synthesis and characterisation of metal complexes that contain chemically reduced bipyridyl ligands. The crystal structures of twenty-six novel complexes are reported alongside detailed discussions on the electronic and spectroscopic effects and trends associated with the different oxidation states within these species.

Chapter One introduces the isomers of bipyridine and their redox chemistry, the concept of non-innocent ligands and the sp...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Research group:
The Goicoechea Group
Oxford college:
Oriel College
Role:
Author

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Division:
MPLS
Department:
Chemistry
Role:
Supervisor
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK

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