Journal article
Voltammetry of porous layers: Staircase vs analog voltammetry
- Abstract:
- The use of staircase ramps for cyclic voltammetry rather than true linear analog ramps can lead to significant misinterpretation of the signals recorded for the measurement of diffusional redox species with either reversible or irreversible electrode kinetics measured at electrodes modified with porous layers. Most notably a large perturbation of the expected peak current is apparent which can preclude the extraction of meaningful data, for example in respect of surface coverages or in the identification of electro-catalysis.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Accepted manuscript, pdf, 1.3MB)
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- Publisher copy:
- 10.1016/j.jelechem.2016.06.003
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Authors
Funding
Bibliographic Details
- Publisher:
- Elsevier Publisher's website
- Journal:
- Journal of Electroanalytical Chemistry Journal website
- Volume:
- 776
- Pages:
- 25-33
- Publication date:
- 2016-06-01
- Acceptance date:
- 2016-06-07
- DOI:
- ISSN:
-
1572-6657
- Source identifiers:
-
632154
Item Description
- Keywords:
- Pubs id:
-
pubs:632154
- UUID:
-
uuid:494c274b-7825-43a1-ae14-eb7d7cc78743
- Local pid:
- pubs:632154
- Deposit date:
- 2016-07-05
Terms of use
- Copyright holder:
- Elsevier BV
- Copyright date:
- 2016
- Notes:
- © 2016 Elsevier B.V. All rights reserved.
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