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Detection of aryllead(IV) carboxylates and their solvent adducts by ESI-mass spectrometry

Abstract:

The successful detection for the first time of some aryllead(IV) carboxylates by electrospray ionisation mass spectrometry (ESI-MS) is reported; in the presence of excess carboxylate ligand, these compounds gave a reliable [M + Na]+ signal. These conditions appear to be generally suitable for the observation of organolead derivatives, and may find wider application for the reliable detection of other heavy main group and transition organometallic compounds. Furthermore, under these conditions...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
645
Issue:
1-2
Pages:
176-182
Publication date:
2002-02-15
DOI:
ISSN:
0022-328X
Source identifiers:
38157
Language:
English
Keywords:
Pubs id:
pubs:38157
UUID:
uuid:49e56910-3581-4675-9551-bda8ea082dac
Local pid:
pubs:38157
Deposit date:
2012-12-19

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