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Studies on the reactivity of [Ge9]4- towards [Fe(cot)(CO)3]: synthesis and characterization of [Ge8Fe(CO)3]3- and of the anionic organometallic species [Fe(cot)(CO)3]-.

Abstract:

Reaction of cyclooctatetraene (COT) iron(II) tricarbonyl, [Fe(cot)(CO)(3)], with one equivalent of K(4)Ge(9) in ethylenediamine (en) yielded the cluster anion [Ge(8)Fe(CO)(3)](3-) which was crystallographically-characterized as a [K(2,2,2-crypt)](+) salt in [K(2,2,2-crypt)](3)[Ge(8)Fe(CO)(3)]. The chemically-reduced organometallic species [Fe(η(3)-C(8)H(8))(CO)(3)](-) was also isolated as a side-product from this reaction as [K(2,2,2-crypt)][Fe(η(3)-C(8)H(8))(CO)(3)]. Both species were furthe...

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Publication status:
Published

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Publisher copy:
10.1002/chem.201000507

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
16
Issue:
36
Pages:
11145-11150
Publication date:
2010-09-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Source identifiers:
90955
Language:
English
Keywords:
Pubs id:
pubs:90955
UUID:
uuid:4e60daa1-6526-48b2-a431-b93a7d2d51de
Local pid:
pubs:90955
Deposit date:
2012-12-19

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