Journal article
Studies on the reactivity of [Ge9]4- towards [Fe(cot)(CO)3]: synthesis and characterization of [Ge8Fe(CO)3]3- and of the anionic organometallic species [Fe(cot)(CO)3]-.
- Abstract:
-
Reaction of cyclooctatetraene (COT) iron(II) tricarbonyl, [Fe(cot)(CO)(3)], with one equivalent of K(4)Ge(9) in ethylenediamine (en) yielded the cluster anion [Ge(8)Fe(CO)(3)](3-) which was crystallographically-characterized as a [K(2,2,2-crypt)](+) salt in [K(2,2,2-crypt)](3)[Ge(8)Fe(CO)(3)]. The chemically-reduced organometallic species [Fe(η(3)-C(8)H(8))(CO)(3)](-) was also isolated as a side-product from this reaction as [K(2,2,2-crypt)][Fe(η(3)-C(8)H(8))(CO)(3)]. Both species were furthe...
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- Publication status:
- Published
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- Publisher copy:
- 10.1002/chem.201000507
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Bibliographic Details
- Journal:
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Volume:
- 16
- Issue:
- 36
- Pages:
- 11145-11150
- Publication date:
- 2010-09-01
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- Source identifiers:
-
90955
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:90955
- UUID:
-
uuid:4e60daa1-6526-48b2-a431-b93a7d2d51de
- Local pid:
- pubs:90955
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2010
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