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Infrared driven CO oxidation reactions on isolated platinum cluster oxides, Pt(n)O(m)+.

Abstract:

This collaboration has recently shown that infrared excitation can drive decomposition reactions of molecules on the surface of gas-phase transition metal clusters. We describe here a significant extension of this work to the study of bimolecular reactions initiated in a similar manner. Specifically, we have observed the infrared activated CO oxidation reaction (CO(ads) + O(ads) --> CO2(g)) on isolated platinum oxide cations, Pt(n)O(m)+. Small platinum cluster oxides Pt(n)O(m)+ (n = 3-7, m...

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Publication status:
Published

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Publisher copy:
10.1039/c2fd20019h

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Journal:
Faraday discussions
Volume:
157
Pages:
213-225
Publication date:
2012-01-01
DOI:
EISSN:
1364-5498
ISSN:
1359-6640
Source identifiers:
354638
Language:
English
Pubs id:
pubs:354638
UUID:
uuid:4f5b9b92-951d-4e56-840c-b42fd5a60788
Local pid:
pubs:354638
Deposit date:
2013-11-16

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