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Lactone backbone density in rigid electron-deficient semiconducting polymers enabling high n-type organic thermoelectric performance

Abstract:

Three lactone-based rigid semiconducting polymers were designed to overcome major limitations in the development of n-type organic thermoelectrics, namely electrical conductivity and air stability. Experimental and theoretical investigations demonstrated that increasing the lactone group density by increasing the benzene content from 0 % benzene (P-0), to 50 % (P-50), and 75 % (P-75) resulted in progressively larger electron affinities (up to 4.37 eV), suggesting a more favorable doping proce...

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Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1002/ange.202113078

Authors


Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie Journal website
Volume:
134
Issue:
7
Article number:
e202113078
Publication date:
2021-12-18
Acceptance date:
2021-11-18
DOI:
EISSN:
1521-3757
ISSN:
0044-8249
Language:
German
Keywords:
Pubs id:
1225429
Local pid:
pubs:1225429
Deposit date:
2021-12-16

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