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Accurate and unequivocal determination of the crystal-field parameters of lanthanide ions via a multitechnique approach

Abstract:

Understanding the crystal field of lanthanide complexes is pivotal for the testing of Stevens operator equivalents and the development of lanthanide-based molecular magnets. Intense theoretical investigation is aimed at the determination of the Hamiltonian parameters, but accurate experimental tests often suffer from overparametrization. Because of this, clear-cut experimental determinations are missing even high-symmetry environments. Here we present a detailed study of the crystal-field par...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1103/PhysRevB.99.134410

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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
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Publisher:
American Physical Society Publisher's website
Journal:
Physical Review B Journal website
Volume:
99
Issue:
13
Article number:
134410
Publication date:
2019-04-05
Acceptance date:
2019-08-02
DOI:
ISSN:
2469-9950 and 1098-0121
Source identifiers:
982661
Pubs id:
pubs:982661
UUID:
uuid:57d3b0ae-279a-49f1-9279-895dda86bc7c
Local pid:
pubs:982661
Deposit date:
2019-03-14

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