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Chemical reactivity on gas-phase metal clusters driven by blackbody infrared radiation

Abstract:

We report the observation of chemical reactions in gas-phase Rhn(N2O)m + complexes driven by absorption of blackbody radiation. The experiments are performed under collision-free conditions in a Fourier transform ion cyclotron resonance mass spectrometer. Mid-infrared absorption by the molecularly adsorbed N2O moieties promotes a small fraction of the cluster distribution sufficiently to drive the N2O decomposition reaction, leading to the production of cluster oxides and the release of molec...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.201409483

Authors


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Engineering and Physical Sciences Research Council More from this funder
Publisher:
Wiley-VCH Publisher's website
Journal:
Angewandte Chemie - International Edition Journal website
Volume:
54
Issue:
4
Pages:
1357-1360
Publication date:
2015-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
506147
Pubs id:
pubs:506147
UUID:
uuid:5ad716c3-edc9-4be9-9a2c-d8acd0606d78
Local pid:
pubs:506147
Deposit date:
2015-08-31

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