Reactions of allenylpalladium intermediates in organic synthesis
This thesis describes our examination of the reactivity of allenylpalladium intermediates generated from the reaction of palladium(0) with propargylic electrophiles.
Chapter 1 provides a general overview of the literature reported to date concerning the nature and reactivity of allenylpalladium intermediates.
The coupling of a variety of propargylic electrophiles with aryl boronic acids to form allenes is examined in Chapter 2. However, when employing diastereomerically pure ...Expand abstract
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- University of Oxford
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- Daniels, D
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