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Thesis

Reactions of allenylpalladium intermediates in organic synthesis

Abstract:

This thesis describes our examination of the reactivity of allenylpalladium intermediates generated from the reaction of palladium(0) with propargylic electrophiles.

Chapter 1 provides a general overview of the literature reported to date concerning the nature and reactivity of allenylpalladium intermediates.

The coupling of a variety of propargylic electrophiles with aryl boronic acids to form allenes is examined in Chapter 2. However, when employing diastereomerically pure ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Pembroke College
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor
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Funding agency for:
Daniels, D
Grant:
EP/E055273/1
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford

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