Journal article
Framework flexibility of ZIF-8 under liquid intrusion: discovering time-dependent mechanical response and structural relaxation
- Abstract:
-
The structural flexibility of a topical zeolitic imidazolate framework with sodalite topology, termed ZIF-8, has been elucidated through liquid intrusion under moderate pressures (i.e. tens of MPa). By tracking the evolution of water intrusion pressure under cyclic conditions, we interrogate the role of the gate-opening mechanism controlling the size variation of the pore channels of ZIF-8. Interestingly, we demonstrate that its channel deformation is recoverable through structural relaxation...
Expand abstract
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Accepted manuscript, pdf, 697.8KB)
-
(Accepted manuscript, pdf, 533.1KB)
-
- Publisher copy:
- 10.1039/c8cp00447a
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Funding
King's College London
More from this funder
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Physical Chemistry Chemical Physics Journal website
- Volume:
- 20
- Issue:
- 15
- Pages:
- 10108-10113
- Publication date:
- 2018-03-09
- Acceptance date:
- 2018-03-09
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
- Pmid:
-
29589013
- Source identifiers:
-
832478
Item Description
- Language:
- English
- Pubs id:
-
pubs:832478
- UUID:
-
uuid:612f6fe4-57f5-4a88-b047-e319bcbf663a
- Local pid:
- pubs:832478
- Deposit date:
- 2018-05-09
Terms of use
- Copyright holder:
- Sun et al
- Copyright date:
- 2018
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from the Royal Society of Chemistry at: https://doi.org/10.1039/c8cp00447a
If you are the owner of this record, you can report an update to it here: Report update to this record