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Probing the structures of gas-phase rhodium cluster cations by far-infrared spectroscopy.

Abstract:

The geometric structures of small cationic rhodium clusters Rh(n)(+) (n = 6-12) are investigated by comparison of experimental far-infrared multiple photon dissociation spectra with spectra calculated using density functional theory. The clusters are found to favor structures based on octahedral and tetrahedral motifs for most of the sizes considered, in contrast to previous theoretical predictions that rhodium clusters should favor cubic motifs. Our findings highlight the need for further de...

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Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1063/1.3509778

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Publisher:
AIP Publishing Publisher's website
Journal:
Journal of Chemical Physics Journal website
Volume:
133
Issue:
21
Pages:
214304
Publication date:
2010-12-07
Acceptance date:
2010-10-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Source identifiers:
107011
Language:
English
Keywords:
Pubs id:
pubs:107011
UUID:
uuid:6686cbc5-76f2-4363-b7b0-fc63c9dc620d
Local pid:
pubs:107011
Deposit date:
2012-12-19

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