Journal article
Probing the structures of gas-phase rhodium cluster cations by far-infrared spectroscopy.
- Abstract:
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The geometric structures of small cationic rhodium clusters Rh(n)(+) (n = 6-12) are investigated by comparison of experimental far-infrared multiple photon dissociation spectra with spectra calculated using density functional theory. The clusters are found to favor structures based on octahedral and tetrahedral motifs for most of the sizes considered, in contrast to previous theoretical predictions that rhodium clusters should favor cubic motifs. Our findings highlight the need for further de...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(pdf, 1.2MB)
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- Publisher copy:
- 10.1063/1.3509778
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Authors
Bibliographic Details
- Publisher:
- AIP Publishing Publisher's website
- Journal:
- Journal of Chemical Physics Journal website
- Volume:
- 133
- Issue:
- 21
- Pages:
- 214304
- Publication date:
- 2010-12-07
- Acceptance date:
- 2010-10-01
- DOI:
- EISSN:
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1089-7690
- ISSN:
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0021-9606
- Source identifiers:
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107011
Item Description
- Language:
- English
- Keywords:
- Pubs id:
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pubs:107011
- UUID:
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uuid:6686cbc5-76f2-4363-b7b0-fc63c9dc620d
- Local pid:
- pubs:107011
- Deposit date:
- 2012-12-19
Terms of use
- Copyright holder:
- American Institute of Physics
- Copyright date:
- 2010
- Notes:
- © 2010 American Institute of Physics
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