Journal article icon

Journal article

Synthesis, characterisation and redox properties of anti-bimetallic permethylpentalene complexes

Abstract:

We report a series of anti-bimetallic transition metal complexes based on the permethylpentanyl (Pn*, C8Me6) ligand: anti-(MCpR5)2Pn* (where M = Fe, Co and Ni and R = H or Me). Compounds (FeCp*)2Pn* (1), (CoCp*)2Pn* (2), (NiCp*)2Pn* (3), (CoCp)2Pn* (4) and (NiCp)2Pn* (5) were fully characterised by NMR spectroscopy, X-ray crystallography, DFT calculations and cyclic voltammetry. All anti-(MCpR5)Pn* structures have diamagnetic ground states. 1, 2 and 4 have isolated non-degenerate ground state...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Publisher copy:
10.1039/c8dt05054f

Authors


More by this author
Role:
Author
ORCID:
0000-0003-4402-0313
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Oxford college:
St Hugh's College
Role:
Author
ORCID:
0000-0002-2933-2303
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0003-2044-9203
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0003-2062-9546
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Balliol College
Role:
Author
ORCID:
0000-0001-8054-8751
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
48
Issue:
13
Pages:
4263-4273
Publication date:
2019-02-27
Acceptance date:
2019-02-26
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Pmid:
30848268
Source identifiers:
983448
Language:
English
Keywords:
Pubs id:
pubs:983448
UUID:
uuid:675d5f4a-b958-4699-b1f8-cd9cee04fd10
Local pid:
pubs:983448
Deposit date:
2019-04-08

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP