Journal article
Synthesis, characterisation and redox properties of anti-bimetallic permethylpentalene complexes
- Abstract:
-
We report a series of anti-bimetallic transition metal complexes based on the permethylpentanyl (Pn*, C8Me6) ligand: anti-(MCpR5)2Pn* (where M = Fe, Co and Ni and R = H or Me). Compounds (FeCp*)2Pn* (1), (CoCp*)2Pn* (2), (NiCp*)2Pn* (3), (CoCp)2Pn* (4) and (NiCp)2Pn* (5) were fully characterised by NMR spectroscopy, X-ray crystallography, DFT calculations and cyclic voltammetry. All anti-(MCpR5)Pn* structures have diamagnetic ground states. 1, 2 and 4 have isolated non-degenerate ground state...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Publisher copy:
- 10.1039/c8dt05054f
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Authors
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Dalton Transactions Journal website
- Volume:
- 48
- Issue:
- 13
- Pages:
- 4263-4273
- Publication date:
- 2019-02-27
- Acceptance date:
- 2019-02-26
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- Pmid:
-
30848268
- Source identifiers:
-
983448
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:983448
- UUID:
-
uuid:675d5f4a-b958-4699-b1f8-cd9cee04fd10
- Local pid:
- pubs:983448
- Deposit date:
- 2019-04-08
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- Copyright date:
- 2019
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