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Magnesium, calcium and zinc [N2N'] heteroscorpionate complexes

Abstract:

A new family of sterically demanding N2N′ heteroscorpionate pro-ligands (HC(tBu2pz)2SiMe2N(H)R (R = iPr, tBu, Ph, Xyl)) has been prepared via a straightforward modular synthetic route. An extensive study into the synthesis and characterisation of lithium, magnesium, calcium and zinc complexes supported by both 3,5-tBu and 3,5-Me substituted N2N′ ligand families has been conducted. Attempted deprotonation of the pro-ligands with nBuLi afforded the corresponding lithium salts Li{HC(tBu2pz)2SiMe...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C8DT04985H

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More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Balliol College
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
St Edmund Hall
Role:
Author
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
48
Pages:
4124-4138
Publication date:
2019-01-08
Acceptance date:
2019-01-07
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Source identifiers:
957809
Pubs id:
pubs:957809
UUID:
uuid:6b6d34f6-a1cc-41b5-96fc-712dba147181
Local pid:
pubs:957809
Deposit date:
2019-01-08

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