Journal article
Communications: The structure of Rh(8) (+) in the gas phase.
- Abstract:
-
The geometric structure of the Rh(8) (+) cation is investigated using a combination of far-infrared multiple photon dissociation spectroscopy and density functional theory (DFT) calculations. The energetic ordering of the different structural motifs is found to depend sensitively on the choice of pure or hybrid exchange functionals. Comparison of experimental and calculated spectra suggests the cluster to have a close-packed, bicapped octahedral structure, in contrast to recent predictions of...
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- Publication status:
- Published
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- Publisher copy:
- 10.1063/1.3285266
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Authors
Bibliographic Details
- Journal:
- Journal of chemical physics
- Volume:
- 132
- Issue:
- 1
- Pages:
- 011101
- Publication date:
- 2010-01-01
- DOI:
- EISSN:
-
1089-7690
- ISSN:
-
0021-9606
- Source identifiers:
-
46212
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:46212
- UUID:
-
uuid:6f95355c-a206-4fa3-978f-da88abd21cf0
- Local pid:
- pubs:46212
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2010
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