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Ring-opening polymerisation of low-strain nickelocenophanes: Synthesis and magnetic properties of polynickelocenes with carbon and silicon main chain spacers

Abstract:

Polymetallocenes based on ferrocene, and to a lesser extent cobaltocene, have been well-studied, whereas analogous systems based on nickelocene are virtually unexplored. We have previously shown that poly(nickelocenylpropylene) [Ni(η5-C5H4)2(CH2)3]n is formed as a mixture of cyclic (6x) and linear (7) components by the ring-opening polymerisation (ROP) of tricarba[3]nickelocenophane [Ni(η5-C5H4)2(CH2)3] (5). Herein we demonstrate the generality of this approach to main-chain polynickelocenes ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/chem.201804326

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Publisher:
Wiley Publisher's website
Journal:
Chemistry Journal website
Volume:
25
Issue:
4
Pages:
1044-1054
Publication date:
2018-10-10
Acceptance date:
2018-10-08
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pmid:
30304580
Source identifiers:
929671
Language:
English
Keywords:
Pubs id:
pubs:929671
UUID:
uuid:709cb2be-428b-474b-a126-ef17fae8cdd8
Local pid:
pubs:929671
Deposit date:
2018-10-29

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