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Synthesis and characterization of permethylpentalene titanium aryloxide and alkoxide complexes

Abstract:

A series of titanium complexes containing the permethylpentalene ligand (C8Me62−; Pn∗) – Pn∗Ti(O-2,6-Me-C6H3)Cl (1), Pn∗Ti(O-2,4-tBu-C6H3)Cl (2), Pn∗Ti(OtBu)Cl (3), Pn∗Ti(O-2,6-Me-C6H3)2(4), Pn∗Ti(OtBu)2(5) – or the (hydro)permethylpentalene ligand (C8Me6H−; Pn∗(H)) – Pn∗(H)Ti(O-2,6-Me-C6H3)Cl2(6) and Pn∗(H)Ti(O-2,6-Me2-C6H3)3(7) – were prepared by the reaction of [Pn∗TiCl(μ-Cl)]2with the corresponding potassium salt or alcohol. All complexes have been characterized by single crystal X-ray di...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.poly.2018.09.068

Authors


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SCG Chemicals Co., Ltd More from this funder
Publisher:
Elsevier Publisher's website
Journal:
Polyhedron Journal website
Volume:
157
Pages:
146-151
Publication date:
2018-09-29
Acceptance date:
2018-09-24
DOI:
EISSN:
1873-3719
ISSN:
0277-5387
Source identifiers:
934796
Keywords:
Pubs id:
pubs:934796
UUID:
uuid:8a740afd-7d35-48cf-b5a7-bd4e4403e69b
Local pid:
pubs:934796
Deposit date:
2018-10-29

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