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Thesis

Organosilicon reagents in carbon-carbon bond forming reactions: towards the total synthesis of incednine

Abstract:

This thesis investigates a total synthesis of the incednine aglycon by utilising alkenylsilane reagents to assemble the pentaenyl and tetraenyl systems through cross-coupling reactions. The early chapters develop methodology to access both cyclic alkenylsiloxanes and functionalised (E)-alkenylsilanes by the controlled hydrogenation of alkynylsiloxanes and silylolefination of aldehydes, respectively, and culminate in the synthesis of a C6-C13 bis(alkenylsilane)incednine fragment (S...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Research group:
Edward Anderson
Oxford college:
Merton College
Role:
Author

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Role:
Supervisor
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Funding agency for:
Lim, D
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK
Language:
English
Keywords:
Subjects:
UUID:
uuid:beb3e9cb-087d-4c96-97f4-da611d08f9f9
Local pid:
ora:8967
Deposit date:
2014-09-19

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