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Collisional activation of N2O decomposition and CO oxidation reactions on isolated rhodium clusters.

Abstract:

The reactions of nitrous oxide decorated rhodium clusters, RhnN2O(+) (n = 5, 6), have been studied by Fourier transform ion cyclotron resonance mass spectrometry. Collision induced dissociation with Ar is shown to lead to one of two processes; desorption of the intact N2O moiety (indicating molecular adsorption in the parent cluster) or N2O decomposition liberating molecular nitrogen with the latter becoming increasingly dominant at higher collision energies. Consistent with the results of ea...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/jp405267p

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Publisher:
American Chemical Society Publisher's website
Journal:
Journal of Physical Chemistry A Journal website
Volume:
117
Issue:
36
Pages:
8855-8863
Publication date:
2013-09-03
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
Source identifiers:
421070
Language:
English
Keywords:
Pubs id:
pubs:421070
UUID:
uuid:cc08a54d-3aaa-473f-9258-f3ea33bae389
Local pid:
pubs:421070
Deposit date:
2013-11-17

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