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Dual oxidation state tandem catalysis in the palladium-catalyzed isomerization of alkynyl epoxides to furans

Abstract:

A two-catalyst system consisting of different oxidation states of palladium is described, which mediates the isomerization of alkynyl epoxides to furans. In a process termed “dual oxidation state tandem catalysis”, a multistep isomerization pathway is delineated in which the different metal oxidation states and ligands play independent mechanistic roles, but which, in combination, enable the use of milder reaction conditions and lower catalyst loadings than a single catalyst in isolation. In ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acscatal.8b02248

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Jesus College
Role:
Author
ORCID:
0000-0002-4149-0494
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More from this funder
Funding agency for:
Anderson, EA
Grant:
EP/M019195/1
More from this funder
Funding agency for:
Arroniz, C
Grant:
EP/M019195/1
More from this funder
Funding agency for:
Chaubet, G
Grant:
656012
Publisher:
American Chemical Society Publisher's website
Journal:
ACS Catalysis Journal website
Volume:
8
Issue:
9
Pages:
8290–8295
Publication date:
2018-08-03
Acceptance date:
2018-08-03
DOI:
EISSN:
2155-5435
Source identifiers:
920477
Keywords:
Pubs id:
pubs:920477
UUID:
uuid:d88968d1-7110-4afc-8b5e-d5805762dd22
Local pid:
pubs:920477
Deposit date:
2018-09-20

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