Thesis
Solution reactivity studies of group 14 zintyl clusters towards organometallic reagents
- Abstract:
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The group 14 Zintl clusters [E₉]⁴⁻ (E = Ge, Sn, Pb) have been reacted with organometallic reagents in solution in the presence of alkali metal cation sequestering agents. The synthesis, characterisation and reactivity studies of the resultant complexes are reported herein.
These negatively charged clusters reductively cleave one of the M–C bonds in the group 12 homoleptic organometallic reagents MR₂ (M = Zn, Cd; R = Ph, mes, ⁱPr) to yield η⁴-coordinated functionalised clusters closo-...
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Bibliographic Details
- Publication date:
- 2012
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- Oxford University, UK
Item Description
- Language:
- English
- Keywords:
- Subjects:
- UUID:
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uuid:e5e50d36-579d-4d32-9de5-470bea1277d8
- Local pid:
- ora:6497
- Deposit date:
- 2012-10-05
Terms of use
- Copyright holder:
- Zhou, B
- Copyright date:
- 2012
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