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A general route to bicyclo[1.1.1]pentanes through photoredox catalysis

Abstract:

Photoredox catalysis has transformed the landscape of radical-based synthetic chemistry. Additions of radicals generated through photoredox catalysis to carbon-carbon π-bonds are well-established; however, this approach has yet to be applied to the functionalization of carbon-carbon σ-bonds. Here, we report the first such use of photoredox catalysis to promote the addition of organic halides to the carbocycle [1.1.1]propellane; the product bicyclo[1.1.1]pentanes (BCPs) are motifs of high impo...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acscatal.9b03190

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Publisher:
American Chemical Society Publisher's website
Journal:
ACS Catalysis Journal website
Volume:
9
Issue:
10
Pages:
9568-9574
Publication date:
2019-09-20
DOI:
ISSN:
2155-5435
Source identifiers:
1067558
Pubs id:
pubs:1067558
UUID:
uuid:f6e115cf-3ac8-4dda-8e63-93acfc53b9ce
Local pid:
pubs:1067558
Deposit date:
2019-10-31

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