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Experimental and theoretical studies of the Xe-OH(A/X) quenching system

Abstract:

New multi-reference, global ab initio potential energy surfaces (PESs) are reported for the interaction of Xe atoms with OH radicals in their ground X2Π and excited A2Σ+ states, together with the non-adiabatic couplings between them. The 2A' excited potential features a very deep well at the collinear Xe-OH configuration whose minimum corresponds to the avoided crossing with the 1A' PES. It is therefore expected that, as with collisions of Kr + OH(A), electronic quenching will play a major ro...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.5051068

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Oxford college:
Jesus College
Role:
Author
Spanish Ministry of Economy and Innovation More from this funder
US National Science Foundation More from this funder
Publisher:
American Institute of Physics Publisher's website
Journal:
Journal of Chemical Physics Journal website
Volume:
149
Issue:
18
Article number:
184301
Publication date:
2018-11-08
Acceptance date:
2018-10-19
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Pmid:
30441911
Language:
English
Keywords:
Pubs id:
pubs:944882
UUID:
uuid:fc84e764-52a4-44e6-a09e-b239d6bfbf1a
Local pid:
pubs:944882
Source identifiers:
944882
Deposit date:
2018-11-22

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