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Product lambda-doublet ratios as an imprint of chemical reaction mechanism

Abstract:

In the last decade, the development of theoretical methods has allowed chemists to reproduce and explain almost all of the experimental data associated with elementary atom plus diatom collisions. However, there are still a few examples where theory cannot account yet for experimental results. This is the case for the preferential population of one of the Λ-doublet states produced by chemical reactions. In particular, recent measurements of the OD((2)Π) product of the O((3)P)+D2 reaction have...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/ncomms13439

Authors


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Institution:
University of Oxford
Oxford college:
Jesus College
Role:
Author
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Funding agency for:
Brouard, M
Grant:
EP/L005913/1
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Grant:
CTQ2012-37404-C02,CTQ2015-65033-P
ConsoliderIngenio2010CSD2009-00038
Publisher:
Nature Publishing Group Publisher's website
Journal:
Nature Communications Journal website
Volume:
7
Article number:
13439
Publication date:
2016-11-11
Acceptance date:
2016-10-04
DOI:
ISSN:
2041-1723
Source identifiers:
659983
Language:
English
Pubs id:
pubs:659983
UUID:
uuid:fd9d0fd8-01d2-4876-826d-029327bbeb5c
Local pid:
pubs:659983
Deposit date:
2016-11-19

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