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Differential steric effects in the inelastic scattering of NO(X) + Ar: spin-orbit changing transitions

Abstract:

Spin-orbit changing transitions for bond-axis oriented collisions of NO(X) with Ar have been investigated with full quantum state selection via a crossed molecular beam experiment at collision energies of 532 cm−1 and 651 cm−1. NO(X) molecules were selected in their ground rotational state (Ω = 0.5, j = 0.5, f) before being adiabatically oriented using a static electric field, such that either the N- or O-end of the molecule was directed towards the incoming Ar atom. After collision, NO(X, Ω′...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c8cp06225k

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Oxford college:
Jesus College
Role:
Author
ORCID:
0000-0003-3421-0850
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Role:
Author
ORCID:
0000-0002-2384-7744
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Role:
Author
ORCID:
0000-0001-5718-5905
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National Basic Research Program of China More from this funder
National Science Foundation of China More from this funder
Spanish Ministry of Economy and Innovation More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Physical Chemistry Chemical Physics Journal website
Volume:
21
Issue:
26
Pages:
14173-14185
Publication date:
2018-11-10
Acceptance date:
2018-11-07
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Pmid:
30444242
Source identifiers:
944881
Language:
English
Keywords:
Pubs id:
pubs:944881
UUID:
uuid:ff684de3-e0e7-4e4b-b754-cdcbaf14a5b2
Local pid:
pubs:944881
Deposit date:
2018-11-22

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